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Carlos Diaz

Chemistry
University of Chile

Publications

PUBLICACIONES


1.- G. González, C. Díaz and S. Copaja
“Reaktionen von Diaminosulfanen mit Kupfer (II) - Salzen”
Monatshefte fur Chemie, 114, 177- 183, (1983)

2.- C. Díaz V.
“Espectros Infrarrojos de la N,N'-tiobisdimetilamina y sus derivados”.
Acta Sudamericana de Química, 3, 15-20, (1983)

3.- C. Díaz, E. Clavijo and G. González
“Infrared and Raman study of thiobisamines”
Spectrochim. Acta, 39 A, 537-540, (1983)

4.- C. Díaz, S. Copaja and G. González
“Donor-acceptor molecular complexes of the thiobisphaltalimide with diphenylamine and potassium thiocyanate”
Acta Sudamericana de Química, 4, 47-52, (1984)

5.- C. Díaz and G. González
“Sulphur (II) - metal coordination compounds. Group VI metal carbonyl complexes with N,N' - thiobisamine ligands”.
Inorg. Chimica Acta, 85 (1), 61-64, (1984)

6.- C. Díaz, S. Copaja and G. González
“Alkoxythioamines”
Phosphorus and Sulfur, 22, 317-321, (1985)

7.- C. Díaz V.
“A characteristic redox reaction for N,N' thiobisamines and some other S(II) compounds”
Polyhedron, 4, (7), 1269-1270, (1985)

8.- C. Díaz V.
"Synthesis of disubstituted ammonium trichlorodicuprate (I) from the reaction of CuCl2.2H2O with N,N'thiobisamines".
Polyhedron, 5, 655-657, (1986)


9.- C. Díaz V.
"Unexpected reaction of sulphur dichloride with Cr(CO)5THF: A Cr(III)product without carbon monoxide as ligand".
Polyhedron, 5, 2001-2003, (1986)

10.- I. Chadwick, C. Díaz, G. González, M.A. Santa Ana and N. Yutronic
"Electrochemical oxidation of monosubstituted chromium carbonyl complexes. Ligand and solvent effect".
J. Chem. Soc., Dalton Trans., 1867-1871, (1986)

11.- C. Díaz and N. Yutronic
"The 1A1  1E transition as a measure of the -acceptor ability in M(CO)5L complexes"
Polyhedron, 6, 503-506, (1987)

12.- C. Díaz and N. Yutronic
"Coordination properties of some solvents in Cr(CO)5L complexes".
Polyhedron, 7, 673-677, (1988)

13.- G. González, C. Díaz and H. Binder
"ESCA studies of N,N'-thiobisamines and of their chromium, carbonyl complexes".
Zeitschrift für Natuforschung, 43B, 513-516, (1988)

14.- C. Díaz and A. Arancibia
"Spectroscopic properties of N,N'-dithiobisamines and their cyclic analogues N,N'- dialkylcyclotetrasulfur-1,4-diimides".
Phosphorus and Sulphur, 44, 1 - 8, (1989)

15.- C. Díaz V.
"Sulphur(II) compounds as ligands. Chromium pentacarbonyl complexes with alkoxythioamines as ligands".
Sulfur Letters, 9, 1 - 8, (1989)

16.- C. Díaz and N. Yutronic
"Identification of lowest excited state in the complex Cr(CO)5PBu3"
Polyhedron, 8, 1099-1102, (1989)

17.- M.L. Rodríguez, C. Ruiz-Pérez, J. Brito, C. Díaz, J. Cuevas, G. González and V.Manríquez
"Coordination of (N,-N'-Dibenzyl)-benzene sulfenamide, via sulfur atom. Crystal and Molecular Structure of (C6H5CH2)2NS(C6H5)Cr(CO)5".
J. Organomet. Chem., 377, 235-240, (1989)

18.- C. Díaz V.
"The mass spectral fragmentation of N,N'-Dithiobisamines and their Cyclic Analogues 3,6-Dialkyl-1,2,4,5,3,6-Tetrathiadiazines".
Phosphorus and Sulfur, 48, 141-148, (1990)


19.- C. Díaz V.
"Sulphurating and coordinating properties of N,N'-Thiobismorpholine towards iron Carbonyls".
Polyhedron, 9, 1045-1049, (1990)

20.- C. Díaz, J. Cuevas, G. González
"IR and 'H-NMR characterization of Sulfenamides".
Sulfur Letter, 11, 145-155, (1990)

21.- Gabino A. Carriedo, M. Carmen Crespo, Carlos Díaz and Víctor Riera
"Synthesis of new carbonyl complexes of manganese (I) containing monodentate Ph2PCH2PPh2(dppm)".
J. Organomet. Chem., 397, 309-312, (1990)

22.- M.L. Rodríguez, I. Brito, F.V. Rodríguez-Romero, V. Manríquez, G. González and
C. Díaz
"Structure of Pentacarbonyl-(morpholin) Chromium (O)".
Acta Cryst., C47, 858-860, (1991)

23.- C. Díaz, R. Contreras, G. González and A. Aizman
"Reactivity of Sulfur(II) compounds. Chemical properties and frontier molecular orbital analysis".
Phosphorus and Sulfur, 55, 219-288, (1991)

24.- C. Díaz, J. Cuevas and G. González
"Sulfenamides as ligands in transition metal chemistry. Pentacarbonyl (Sulfenamide) Chromium (0) complexes".
Z. Anorg. Allg. Chem., 592, 7-16, (1991)

25.- C. Díaz V.
"Redox and coordinated properties of N,N'-Dithiobisamines: Oxidative Desulphuration by Cu (II) ions and Cr(CO)5 S2(NR2) 2 complexes".
Polyhedron, 10, 1319-1326, (1991)

26.- C. Díaz and N. Yutronic.
"The S-S Bond in N,N'-Dithiobisamines. A Raman study".
Phosphorus, Sulfur and Silicon, 62, 219-223, (1991)

27.- G. Barrado, G.A. Carriedo, C. Díaz and V. Riera
"Synthesis and oxidation of cationic heterobinuclear Cyanide-Bridged Complexes of Manganese and iron".
Inorganic Chemistry, 30, 4416-4420, (1991)

28.- V. Manríquez, C. Díaz, S. Copaja and G. González
“The crystal structure of the Hydrogen Bonded Molecular adduct Thiobisphtalimide. Diphenylamine".
Phosphorus, Sulfur and Silicon, 63, 377-388, (1991).



29.- E. Benavente, C. Díaz and G. González
"Solvent effect on the infrared and 1H-NMR spectra of N,N'- thodianilines".
Phosphorus, Sulfur and Silicon, (1992) 66, 251-256

30.- M.L. Rodríguez, I. Brito, C. Díaz, G. González and V. Manríquez.
"Structure of (N,N'-dicyclohexyl) benzenesulfenamide and its pentacarbonyl chromium (O) complex via sulfur atom".
J. Organometallic Chemistry, 425, 49-58, (1992)

31.- C. Díaz and R. Latorre
"C5H5-diphenylphosphinoethane iron (II) derivatives from
(n-C5H5)Fe(CO)2I.Synthesis and Mössbauer spectra".
Bol. Soc. Chil. Quím., 37, 211-217, (1992)

32.- C. Díaz and N. Yutronic
"Cis-Trans Isomerism in the complex BrMn(CO)2dppm P(OPh)3. An Electronic spectroscopy study".
Spectroscopy Letters 25, 1411-1420, (1992)

33.- C. Díaz, O. Bustos and N. Yutronic
"Interation of thiourea with sulfur divalent compounds: Desulfurization of thiourea by N,N'-Thiobismorpholine".
Phosphorus, Sulfur and Silicon, 78, 207-214, (1993)

34.- C. Díaz, V. Manríquez, G. González, I. Brito and M. López Rodríguez
"Crystal structure of Methylsulfenamide Pentacarbonyl Chromium (0). A complex with a short Cr-S Bond".
Bol. Soc. Chil. Quím., 38, 83-87, (1993)

35.- C. Díaz, N. Yutronic, B. Weiss
"Ionization of the Fe-X bond in polar solvents: a spectroscopic study of CpFe(dppe)X complexes".
Polyhedron, 12 (11), 1403-1407, (1993)

36.- M.M. Campos V., C. Díaz V., K. Figueroa, L. Padilla and N.Lara H.
"Iron (II) and manganese (I) complexes containing diphosphine ligands. An infrared study of BrMn(CO)2 (dpmm)P(OPh)3 and CpFe(dppe)R(R=I, CN)".
Vibrational Spectroscopy, 7, 61-72, (1994)

37.- C. Diáz and A. Arancibia
"Preparation of new cationic complexes [(n5-C5H5)Fe(dppe)L]PF6 with sulphur and other donor ligands".
Polyhedron, 13 (1), 117-123, (1994)

38.- C. Díaz, E. Benavente and G. González
"The first spectroscopic evidence for the existence of substituted thionitrosobenzene, X-C6H4N=S, as an intermediate in the thermal decomposition of N,N-thiodianilines".
Bol. Soc. Chil. Quím., 39, 335-337, (1994)


39.- C. Díaz, E. Benavente and G. González
"N,N'-Thiodianilines. Detection of thionitrosobenzene derivatives".
Phosphorus, Sulfur, and Silicon, 101, 37-46, (1995)

40.- C. Díaz and B. Weiss
"Generation of thionitroso compounds from N,N'-thiodiamines. A molecular orbital study".
Phosphorus, Sulfur, and Silicon, 102, 31-38, (1995)

41.- C. Diaz and C. Leal
"Cis-trans isomeric influence on the reactivity of BrMn(CO)2dppmP(OPh)3 towards dialkylthioethers".
Polyhedron, 14 (3), 425-428, (1995)

42.- C. Díaz and N. Yutronic
"Coordinating properties of some solvents towards the fragment CpFe(dppe)+".
Polyhedron, 15, (5-6), 997-1001, (1996)

43.- Gabino A. Carriedo, Alejandra Arancibia, Carlos Díaz-Valenzuela, Nicolás Yutronic, Enrique Pérez Carreño, Santiago García-Granda.
"Comparison of the oxidation of dinuclear cyclopentadienyl iron diphosphine complexes with the bridging ligands-CN and-C=C (CH2)2CN".
Journal Organometallic Chemistry, 508, 23-30, (1996)

44.- C. Díaz, C. Leal and N. Yutronic
"S-S Cleavage in Disulphides by the Fragment CpFe(dppe)+".
Bol. Soc. Chil. Quím., 41, 099-102, (1996)

45.- C. Díaz, C. Leal and N. Yutronic
"Oxidative addition of disulfides to the fragment CpFe(dppe)+: steric and dielectric medium control on the reaction".
Journal Organometallic Chemistry, 516, 59-64, (1996)

46.- V. Manríquez, C. Díaz, G. González and I. Brito
"Thermal behaviour of benzenesulfenamides and of their chromium carbonyl complexes".
Journal of Thermal Analysis, 46, 1875-1880, (1996),

47.- C. Díaz. and C. Leal
"New Complexes [CpFe(dppe)thiophenes]PF6".
Polyhedron, 15 (17), 2825-2829, (1996)

48.- C. Díaz, and A. Arancibia
"Inclusion Compounds of Half-Sandwich Complexes of Iron With Cyclodextrins: Unprecedented Laminar Structures".
Bol. Soc. Chil. Quím., 41, 291-294, (1996)


49.- C. Díaz
“Sulfur-hydrogen bond activation of thiols by the fragment CpFe(dppe)+: cyclopentadienyl iron (III) thiolate complexes
Polyhedron 16, 7, 999-1002, (1997)

50.- Carlos Díaz and Eyleen Araya
“Monodentated, bridged and chelated behaviour of diphosphines towards the fragment CpFe(dppe)+
Polyhedron 16, 11, 1775-1781, (1997)

51.- C.Díaz and R. Montecinos
“Solvent effect on the oxidative addition of HS-C6H4Br to CpFe (dppe)+. A reaction involving an Fe-S intramolecular electron transfer”.
Bol. Soc. Chil. Quím., 42, 513-518, (1997)

52.- C. Díaz, A. Arancibia
“The cyanide ligand as an efficient bridge in mixed-valence complexes
Inorganica Chimica Acta, 269, 246-252, (1998)

53.- Carlos Díaz and Alejandra Arancibia
“Molecular Encapsulation of Half-Sandwich Complexes of Iron with Cyclodextrins: New Laminar Materials”.
Journal of Inclusion Phenomena and Molecular
Recognition in Chemistry, 30, 127-141 (1998)

54.- C.Díaz, E. Araya and M.A. Santa Ana
“Redox Properties of 17- Electron thiolate Complexes of cyclopentadienyl iron (III)
Polyhedron, 17, 2225-2230, (1998)

55.- Carlos Díaz and Alejandra Arancibia
“An evidence of mixed-valence electron transfer in the inverted Marcus region”.
Bol. Soc. Chil. Quím., 43, 097-102, (1998)

56.- C.Díaz and A. Arancibia
“Monodentate and Bridging Behavior of Dinitriles Ligands Toward the Fragment Cp(dppe)Fe+”.
Bol. Soc. Chil. Quím., 43, 303-314, (1998)

57.- C. Díaz
“A Reversible Oxidative Addition of HSCH2CH2SH to The Fragment CpFe(dppe); Medium Control of the Reaction”
Bol. Soc. Chil. Quím., 43, 477-484, (1998)

58.- C. Díaz
“Identification of Lowest excited States in the Organometallic iron-Nitrile Complexes”.
Bol. Soc. Chil. Quím., 44, 109-115, (1999)


59.- C. Díaz, I. Izquierdo
“Iron and Ruthenium Derivatives of Cyclophosphazenes Coordinated Through Nitrile Spacer Ligands”.
Polyhedron, 18, 1479-1484, (1999)

60.- C. Díaz, I. Izquierdo, F. Mendizábal, N. Yutronic
“Iron and ruthenium organometallic derivatives of spiro-substituted cyclotriphosphazenes bearing nitrile spacer: synthesis and electronic structure”.
Inorganica Chimica Acta, 294, 20-27, (1999)

61.- C. Díaz
“Observation of Stable 17 e Iron (III) Cyclopentadienyl Radical Complexes”.
Bol. Soc. Chil. Quím., 44, 315-320, (1999)

62.- Ivan Brito, C. Díaz, Guillermo González, Matías López Rodríguez and V. Manríquez.
“The Crystal Structure of a Novel Sulfenamide: (N,N-Dibenzyl) Benzenesulfenamide”
Bol. Soc. Chil. Quím., 44, 459-462 (1999)

63.- C. Díaz and A. Arancibia
“TCNE and TCNQ ligands as efficient bridges in mixed-valence complexes containing iron-cyclopentadienyl and other organometallic systems”
Polyhedron, 19, 137-145, (2000)

64.- C. Díaz and A. Pesce.
"S-H Bond Cleavage in Molecules of Biological Interest with Organometallic Iron (II) Complexes".
Applied Organometallic Chemistry, 14, 557-560, (2000)

65.- C. Díaz, I. Izquierdo, M. L. Valenzuela and N. Yutronic.
"Metal-Metal Interaction through CH2-CN bridge: Synthesis and Characterization of [CpM(L2)NCCH2Fc]PF6 Complexes (Fc:ferrocenyl L:1/2 dppe, PPh3 M:Fe , Ru)".
Inorganic Chemistry Comunications 3, 525-529, (2000)

66.- C. Díaz and M. L. Valenzuela
“Dendrimers Based on Cyclophosphazene Unit and Containing Iron (III)”.
Bol. Soc. Chil. Quím., , 45, 527-533, (2000)

67.- C. Díaz and A. Arancibia
“Intervalence electron trasfer through a thiolate bridge ligand: a FIII -S-R-FII mixed valence complex”.
Polyhedron, 19, 2679-2687, (2000)

68.- C. Díaz, E. Spodine, Y. Moreno, A. Arancibia.
“Fe (II) – Fe (III) electronic and magnetic interaction through a thiopyridine bridge”.
Bol. Soc. Chil. Quím., 45, 317-322, (2000)


69.- C. Díaz and A. Gómez
"New ruthenium (II) complexes containing organodisulphide ligands".
J. Coord. Chem., 54, 261-266, (2001)

70.- C. Díaz and F. Mendizábal
“Exponential Decay of a Charge Transfer Induced by Coordination in Organometallic Complexes".
Bol. Soc. Chil. Quím. 46, 293-299, (2001)

71.- K. Costuas, M.L.Valenzuela, A. Vega , Y. Moreno , O. Peña ,E. Spodine , J-Y Saillard and C. Diaz,
"Iron-Iron interaction through an ethanethiolate ligand :a magnetic and theoretical
study"
Inorganica Chimica Acta, 329,129-134, (2002)

72.- C. Díaz, Nancy Cabezas, F. Mendizábal
"New Entry to Piano-Stool Electron Rich (Pentamethyl Cyclopentadienyl) Iron Complexes"
Bol. Soc. Chil. Quím. 47, 213-220, (2002)

73.- C. Díaz and M.L. Valenzuela
"Transition Metal Containing Dendrimers Based on Cyclophosphazene Units.
Polyhedron, 21, 909-915, (2002)

74.- C. Díaz and P. Castillo
"Incorporation of Chromium-Carbonyl Fragments to Bis-Spirocyclophosphazene and Spiro Polyphosphazene Containing Benzylcyanide Spacer"
J. Inorg. Organometallic Polymers. 11, 183-192 (2002)

75.- C. Diaz, P. Castillo, G.A.Carriedo, P.Gomez-Elipe, F.J.Garcia-Alonso
"Cymantrene Derivatives of Oligomers and Polyphosphazene Containing Benzylcyanide spacer"
Macromolec. Phys. and Chem. 203, 1918-1925, (2002)

76.- G.A. Carriedo, F.J. Garcia-Alonso J. L. García Alvarez, C. Diaz, N. Yutronic
"Synthesis and Spectroscopic Properties of a New High Molecular Weight Poly- Spirophosphazene-Oxypyridine Copolymer and its Complexes with W(CO)5 Fragments"
Polyhedron 21, 2587-2592, (2002)

77.- G.A. Carriedo, F.J. Garcia-Alonso, P. A. González, C. Diaz, N. Yutronic
"Synthesis and Spectroscopic Characterization of Cyclic and Polymeric Phosphazenes Bearing Phosphine Complexes"
Polyhedron . 21, 2579-2586, (2002)

78.- G.A. Carriedo, F.J. Garcia-Alonso, P. Gomez -Elipe, C. Diaz and N. Yutronic
"Synthesis and Spectroscopic and Electrochemical Study of Cationic Cyclo-
pentadienyliron(diphosphine) Complexes Supported on a High Molecular Weight
Phosphazenes Polymer through Nitrile Ligands.
Journal of the Chilean Chemical Society 48, 25-28, (2003)

79.- C.Díaz and P.Castillo.
"Synthesis and characterization of soluble polyphosphazenes having pendent Cp*Fe(dppe) groups."
Polymer bulletin. 50, 123-129, (2003)

80.- G.A. Carriedo, F.J. Garcia-Alonso, S. López Vizcaíno , C. Diaz, N. Yutronic
“The reaction of the Bis-spirocyclicphosphazene [N3P3(O2C12H8)2Cl2]
O2C12H8=2,2´-dioxybiphenyl) with thiophenols, in the presence of alkali carbonates “
.- Phosphorus, Sulfur and Silicon 178, 1549-1588, (2003).

81.- C. Díaz, M.L. Valenzuela y M. Barbosa
“A facile organometallic-induced cross-linking of copolymers of Phosphazene”
Material Research Bulletin 39, 9-19, (2004)

82.- C. Díaz , M. Barbosa y Z. Godoy
“ Monobranched and hyperbranched dendrimers based
on cyclophosphazene containing nitrile and phosphine donors and their Fe and Ru
organometallic derivatives”
Polyhedron 23 , 1027-1035, (2004)

83.- C. Diaz, E. Spodine, Y. Moreno E. Carrasco
“A one step functionalization, coordination of N3P3Cl6 using
[CpFe(dppe)SC6H4OH]+
Journal Chilean Chemistry Society, 49, 205-207, (2004)

84.- G. A. Carriedo, José, I. Fidalgo, F.J.Garcia-Alonso, A. Presa, C. Diaz and
M.L.Valenzuela
“Properties of Dioxybiphenyl- and Chiral Dioxybinaphthylphosphazene
Copolymer with Propyl-Carboxylate Units and the Randomization of the
Substitution Reactions of Poly(dichlorophosphazene)”
Macromolecules, 37, 9431-9437, (2004)


85.- Miguel Barbosa, C. Diaz, Maria Ines Toral, Jaime Retuert and Yadienka Martinez
“Synthesis and Characterizatin of Organocyclophosphazene-Silica Composites
New materials able to retain metals Complexes”
Journal of Materials Chemistry, 15, 1360-1368, (2005).

86.- Gabino. A. Carriedo, Francisco .J.Garcia-Alonso, Carlos. Díaz and
Maria Luisa .Valenzuela
“Dioxybiphenyl and Dioxybinaphthy Polyphosphazene Random
CopolymerCarryng Carboxylic Acids and Their Reaction with ε-Caprolactam to Form
Nylon-6-branched Phosphazene Materials”
Macromolecules, 38, 3255-3262, (2005).

87.- C. Díaz, Paola Castillo and Maria Luisa Valenzuela.
Thermolytic Transformations of Organometallic Polymer Containing the Cr(CO)5
Precursor into Nanostructured Chromium Oxide.
Journal of Cluster Science 16, 515-522 (2005).

88.- C. Díaz and Maria Luisa Valenzuela
“Synthesis of Nanostructured Materials by a New Solid State Pyrolysis
Organometallic Method”
Journal Chilean Chemistry Society, 50, 417-419 (2005)
.
89.- Carlos Díaz y Maria Luisa Valenzuela
“Small Molecules and High Polymeric Phosphazenes Containing Oxypyridine Side
Groups and Their Organometallic Derivatives: Useful Precursors to
Nanostructured Materials”
Macromolecules (2006), 39, 103-111.

90.- Gabino Carriedo, F.J.Garcia Alonso, Carlos Díaz and Maria Luisa Valenzuela
“Synthesis and thermal decarbonylation of W(CO)5 complexes supported by
nitrile, pyridine or phosphine ligands to poly-spirophosphazene random
copolymers carrying O-C6H5CO2Pr groups “
Polyhedron (2006), 25, 105-112.






91.- Carlos Díaz and Maria Luisa Valenzuela
“ Photoluminiscent Manganese nanoparticles from solid state Polyphosphazenes
organometallic derivatives”
Journal of Inorganic and Organometallic Polymers (2006), 16, 123-128.


92.- Carlos Diaz, Maria Luisa Valenzuela Gabino Carriedo, F.J.Garcia Alonso and
Alejandro Presa
“ Neutral AuCl complexes supported in linear high molecular weight, poly-
spirophosphazene-phosphine copolymer and its conversion to nanostructured
gold materials
Polymer Bulletin (2006), 57, 913-920.

93.- Carlos Diaz, Domingo Abizanda, Josefina Jimenez, Antonio Laguna and Maria
Luisa Valenzuela
Microsize and Nanosize BPO4 from Pyrolysis of a Carborane Substituted
Polyphosphazene
Journal of Inorganic and Organometallic Polymers (2006), 16, 211-218.

94.- Carlos Díaz, Maria Luisa Valenzuela
Organometallic Derivatives of Polyphosphazenes as Precursors for Metallic
Nonostructured Materials
Journal of Inorganic and Organometallic Polymers (2006), 16,419-435.

95.- Carlos Díaz, Maria Luisa Valenzuela, E. Spodine, Y. Moreno and O. Peña
A Cyclic and Polymeric Phosphazene as Solid State Template for the
Formation of RuO2 Nanoparticles
Journal of Cluster Science (2007) 18, 831-844.

96.- Carlos Díaz, Maria Luisa Valenzuela and Nicolas Yutronic
Polyphosphazenes as Solid Templates for the Formation of Monometallic and
Bimetallic Nanostructures
Journal of Inorganic and Organometallic Polymers (2007), 17, 577-582.

97.- Carlos Díaz, M. Luisa Valenzuela and Luis Zúñiga .
Role of the linking of metallic centers to macromolecular and
oligomeric systems in the pyrolytic products
Journal of the Chilean Chemical Society 53, 1373-1376, (2008).

98.- . Gabino A. Carriedo, M. Luisa Valenzuela, Carlos Díaz Valenzuela and
Svetlana Ushak.
Synthesis phosphazenes)”and pyrolysis of silicon and tin containing
poly(2,2´-dioxy-1,1´biphenoxy- phosphazenes)
European Polymer Journal 44, 686-693, (2008).




99.- Carlos Díaz , Maria Luisa Valenzuela, Svetlana Ushak
Synthesis and characterization of N3P3(O2C12H8)2(OC6H4Si(CH3)3)(OC6H4Br)
and its conversion to nanostructured Si materials
Journal of Cluster Science 19, 471-479 (2008)

100.- Carlos Díaz Maria Luisa Valenzuela Daniel Bravo , Vladimir Lavayen
and Colm O’Dwyer
Synthesis and Characterization of Cyclotriphosphazenes Containing Silicon as
Single Solid-State Precursors for the Formation of Silicon/Phosphorus
Nanostructured Materials
Inorganic Chemistry 47, 11561-11569 (2008)

101.- C. Diaz, M.L. Valenzuela and L. Zuñiga
Role of the Linking of Metallic Centers to Macromolecular and
Oligomeric systems in Pyrolytic products
J. Chilean Chemical Society 53, 1384-1387 (2008)


102.- Carlos Díaz Maria Luisa Valenzuela Svetlana Ushak , Vladimir Lavayen
and Colm O’Dwyer
Nanostructured Silicon containing materials derived from solid
state pyrolysis of sililated polyphosphazene derivatives
Journal of Nanoscience and Nanotechnology 9, 1825-1831, (2009)

103.- Carlos Díaz, Maria Luisa Valenzuela, Luis Zuñiga , and Colm O’Dwyer
Organometallic Derivatives of Cyclotriphosphazenes as precursors of
Nanostructured Metallic Materials: A new solid state method.
Journal of Inorganic and Organometallic Polymers 19, 507-520, (2009).

104.- Carlos Díaz Valenzuela , Gabino A. Carriedo and M. Luisa Valenzuela
Polymer and Oligomer Phosphazene Cymantrene derivatives as solid state
precursors of nanostructured manganese pyrophosphate
Polymer Bulletin 63, 829-835, (2009)

105.- Josefina Jiménez, Antonio Laguna, José Antonio Sanz, Carlos Díaz, María
Luisa Valenzuela, Peter G. Jones
“ Metallocyclo-and Polyphosphazenes Containing Gold Or Silver :Thermolytic
Transformations into Nanostructured Materials “
Chemistry European Journal 15, 13509-135209, (2009).

106.- C. Diaz , M.L.Valenzuela, A. Laguna, V. Lavayen, J. Jimenez, L.Power and C.
O’Dwyer , Metallophosphazene Precursors Routes to the Solid-State
“Deposition of Metallic and Dielectric Microstructures and Nanostructures
on Si and SiO2 “
Langmuir, 26, 10223-10233, (2010).

107.- M.L.Valenzuela and C. Diaz , Copper (II) ions into Polyphosphazenes: Solid-
Like Solution Behavior
J. Inorg. Organomet. Polym. 20, 306-312 (2010).




108 C. Díaz, V. Lavayen and C. O'Dwyer
“Single-Crystal Micro/Nanostructures and Thin Films of Lamellar Molybdenum
Oxide by Solid-State Pyrolysis of Organometallic Derivatives of a
Cyclotriphosphazene”
Journal of Solid State Chemistry 20, 1595-1603 (2010).

109 Carlos Diaz, María Luisa Valenzuela and Pedro Aguirre
Solid-State Gelation of N3P3[NH(CH2)3Si(OEt)3]6-n[X]n = NH(CH2)3Si(OEt)3, NCH3(CH2)3CN and OC6H4(CH2)CN, N= 0 or 3 at the liquid /air interface.
Journal of the Chilean Chemistry Society 55, 415-418 (2010)


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Member since June 8, 2011
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Address: Las Palmeras 3425
Phone: 56-2-9787367
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